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  2. Hund's rule of maximum multiplicity - Wikipedia

    en.wikipedia.org/wiki/Hund's_Rule_of_Maximum...

    For example, the nitrogen atom ground state has three unpaired electrons of parallel spin, so that the total spin is 3/2 and the multiplicity is 4. The lower energy and increased stability of the atom arise because the high-spin state has unpaired electrons of parallel spin, which must reside in different spatial orbitals according to the Pauli ...

  3. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    Each has two electrons of opposite spin in the π* level so that S = 0 and the multiplicity is 2S + 1 = 1 in consequence. In the first excited state, the two π* electrons are paired in the same orbital, so that there are no unpaired electrons. In the second excited state, however, the two π* electrons occupy different orbitals with opposite spin.

  4. Two-dimensional electron gas - Wikipedia

    en.wikipedia.org/wiki/Two-dimensional_electron_gas

    A two-dimensional electron gas (2DEG) is a scientific model in solid-state physics. It is an electron gas that is free to move in two dimensions, but tightly confined in the third. This tight confinement leads to quantized energy levels for motion in the third direction, which can then be ignored for most problems.

  5. Electron mobility - Wikipedia

    en.wikipedia.org/wiki/Electron_mobility

    The electron mobility is defined by the equation: =. where: E is the magnitude of the electric field applied to a material,; v d is the magnitude of the electron drift velocity (in other words, the electron drift speed) caused by the electric field, and

  6. Mass-to-charge ratio - Wikipedia

    en.wikipedia.org/wiki/Mass-to-charge_ratio

    When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.

  7. Molecular Hamiltonian - Wikipedia

    en.wikipedia.org/wiki/Molecular_Hamiltonian

    Their interaction gives a nuclear charge of Z + q, where q = −eN, with N equal to the number of electrons. Electrons and nuclei are, to a very good approximation, point charges and point masses. The molecular Hamiltonian is a sum of several terms: its major terms are the kinetic energies of the electrons and the Coulomb (electrostatic ...

  8. Faraday's laws of electrolysis - Wikipedia

    en.wikipedia.org/wiki/Faraday's_laws_of_electrolysis

    Thus, if x electrons flow, atoms are discharged. Thus, the mass m discharged is = = = where N A is the Avogadro constant; Q = xe is the total charge, equal to the number of electrons (x) times the elementary charge e;

  9. Paschen's law - Wikipedia

    en.wikipedia.org/wiki/Paschen's_law

    However, multiple ionizations occur always in practice. Free electrons at the cathode surface are created by the impacting ions. The problem is that the number of thereby created electrons strongly depends on the material of the cathode, its surface (roughness, impurities) and the environmental conditions (temperature, humidity etc.).