Search results
Results from the WOW.Com Content Network
The Ziegler alcohol synthesis involves oligomerization of ethylene using triethylaluminium followed by oxidation. [2] The triethylaluminium is produced by action of aluminium, ethylene, and hydrogen gas. In the production process, two-thirds of the triethylaluminium produced is recycled back into the reactor, and only one-third is used to ...
In the IUPAC system, the name ethylene is reserved for the divalent group -CH 2 CH 2-. Hence, names like ethylene oxide and ethylene dibromide are permitted, but the use of the name ethylene for the two-carbon alkene is not. Nevertheless, use of the name ethylene for H 2 C=CH 2 (and propylene for H 2 C=CHCH 3) is still prevalent among chemists ...
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH 3 CH 2 OH. It is an alcohol , with its formula also written as C 2 H 5 OH , C 2 H 6 O or EtOH, where Et stands for ethyl .
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...
The reaction typically proceeds by blowing ethylene oxide through the alcohol at 180 °C and under 1-2 bar of pressure, with potassium hydroxide (KOH) serving as a catalyst. [5] The process is highly exothermic (ΔH = -92 kJ/mol of ethylene oxide reacted) and requires careful control to avoid a potentially disastrous thermal runaway. [5]
Ethanol was produced primarily by the sulfuric acid hydration process in which ethylene is reacted with sulfuric acid to produce ethyl sulfate followed by hydrolysis, [10] but this method has been mostly replaced by direct hydration of ethylene. [11] Ethyl sulfate can be produced in a laboratory setting by reacting ethanol with sulfuric acid ...
The Haworth synthesis is a classic method for the synthesis of polycyclic aromatic hydrocarbons. In this reaction, an arene is reacted with succinic anhydride, the subsequent product is then reduced in either a Clemmensen reduction or a Wolff-Kishner reduction. Lastly, a second Friedel-Crafts acylation takes place with addition of acid.
The largest scale application of transesterification is in the synthesis of polyesters. [3] In this application, diesters undergo transesterification with diols to form macromolecules. For example, dimethyl terephthalate and ethylene glycol react to form polyethylene terephthalate and methanol, which is evaporated to drive the reaction forward.