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  2. Wiener index - Wikipedia

    en.wikipedia.org/wiki/Wiener_index

    Butane (C 4 H 10) has two different structural isomers: n-butane, with a linear structure of four carbon atoms, and isobutane, with a branched structure.The chemical graph for n-butane is a four-vertex path graph, and the chemical graph for isobutane is a tree with one central vertex connected to three leaves.

  3. Bond valence method - Wikipedia

    en.wikipedia.org/wiki/Bond_valence_method

    The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...

  4. IUPAC numerical multiplier - Wikipedia

    en.wikipedia.org/wiki/IUPAC_numerical_multiplier

    The numbers 200-900 would be confused easily with 22 to 29 if they were used in chemistry. khīlioi = 1000, diskhīlioi = 2000, triskhīlioi = 3000, etc. 13 to 19 are formed by starting with the Greek word for the number of ones, followed by και (the Greek word for 'and'), followed by δέκα (the Greek word for 'ten').

  5. Geometry index - Wikipedia

    en.wikipedia.org/wiki/Geometry_index

    In coordination chemistry and crystallography, the geometry index or structural parameter (τ) is a number ranging from 0 to 1 that indicates what the geometry of the coordination center is. The first such parameter for 5-coordinate compounds was developed in 1984. [1] Later, parameters for 4-coordinate compounds were developed. [2]

  6. Hydroxyl value - Wikipedia

    en.wikipedia.org/wiki/Hydroxyl_value

    Where HV is the hydroxyl value; V B is the amount (ml) potassium hydroxide solution required for the titration of the blank; V acet is the amount (ml) of potassium hydroxide solution required for the titration of the acetylated sample; W acet is the weight of the sample (in grams) used for acetylation; N is the normality of the titrant; 56.1 is ...

  7. Relative volatility - Wikipedia

    en.wikipedia.org/wiki/Relative_volatility

    Large-scale industrial distillation is rarely undertaken if the relative volatility is less than 1.05. [2] The values of have been correlated empirically or theoretically in terms of temperature, pressure and phase compositions in the form of equations, tables or graph such as the well-known DePriester charts. [4]

  8. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    [1] [2] However the multiplicity equals the number of spin orientations only if S ≤ L. When S > L there are only 2L+1 orientations of total angular momentum possible, ranging from S+L to S-L. [2] [3] The ground state of the nitrogen atom is a 4 S state, for which 2S + 1 = 4 in a quartet state, S = 3/2 due to three unpaired electrons. For an S ...

  9. Defining equation (physical chemistry) - Wikipedia

    en.wikipedia.org/wiki/Defining_equation...

    Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.

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