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Nickel(II) sulfate, or just nickel sulfate, usually refers to the inorganic compound with the formula NiSO 4 (H 2 O) 6. This highly soluble turquoise coloured salt is a common source of the Ni 2+ ion for electroplating. Approximately 40,000 tonnes were produced in 2005. [1]
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
NiSO 3 •3N 2 H 4 · H 2 O: nickel(II) sulfite trihydrazine hydrate rose [5] NiSO 3 •2N 2 H 4 · H 2 O: nickel(II) sulfite dihydrazine hydrate blue [5] NiS 2 O 3 •6H 2 O Nickel(II) thiosulfate hexahydrate 463.03 orthorhombic 9.282 14.44 6.803 912.1 4 2.03 green [6] diaqua (4,4´-dimethylbipyridine- N,N´)(methanol) thiosulfato(S) nickel(II ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The known salts include (NH 4) 2 Ni 2 (SO 4) 3, K 2 Ni 2 (SO 4) 3 and Rb 2 Ni 2 (SO 4) 3, and those of Tl and Cs are predicted to exist. Some minerals are double salts, for example Nickelzippeite Ni 2 (UO 2 ) 6 (SO 4 ) 3 (OH) 10 · 16H 2 O which is isomorphic to cobaltzippeite , magnesiozippeite and zinczippeite , part of the zippeite group.
Tutton's salts are a family of salts with the formula M 2 M'(SO 4) 2 (H 2 O) 6 (sulfates) or M 2 M'(SeO 4) 2 (H 2 O) 6 (selenates). These materials are double salts, which means that they contain two different cations, M + and M' 2+ crystallized in the same regular ionic lattice. [1]
As a mineral the ammonium nickel salt, (NH 4) 2 Ni(SO 4) 2 · 6 H 2 O, can be called nickelboussingaultite. [38] With sodium, the double sulfate is nickelblödite Na 2 Ni(SO 4) 2 · 4 H 2 O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form. [39]
The mechanism for this transformation is shown in the following scheme. Here, the key Ni IV intermediate undergoes a slow homolysis to produce a Ni III intermediate and a trifluoromethyl radical, which can promote propagation of the catalytic cycle. [7] Catalytic trifluoromethylation of arenes via nickel(IV) intermediates.