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Acetonitrile is a byproduct from the manufacture of acrylonitrile by catalytic ammoxidation of propylene. Most is combusted to support the intended process but an estimated several thousand tons are retained for the above-mentioned applications. [15] Production trends for acetonitrile thus generally follow those of acrylonitrile. Acetonitrile ...
Sigma Advanced Genetic Engineering (SAGE) Labs is a division within Sigma-Aldrich that specializes in genetic manipulation of in vivo systems for special research and development applications. It was formed in 2008 to investigate zinc finger nuclease technology and its application for disease research models.
Guanosine monophosphate (GMP), also known as 5′-guanidylic acid or guanylic acid (conjugate base guanylate), is a nucleotide that is used as a monomer in RNA. It is an ester of phosphoric acid with the nucleoside guanosine. GMP consists of the phosphate group, the pentose sugar ribose, and the nucleobase guanine; hence it is a ribonucleotide ...
Trichloroacetonitrile can be obtained by chlorination of acetonitrile on a zinc, copper and alkaline earth metal halide-impregnated activated carbon catalyst at 200–400 °C with a 54% yield. [ 3 ] The high temperatures required by this process favours the formation of byproducts, such as tetrachloromethane .
A colorless liquid, it is derived from acetonitrile (CH 3 CN) by replacement of one H with Cl. In practice, it is produced by dehydration of chloroacetamide. [1] The compound is an alkylating agent, [2] and as such is handled cautiously. Chloroacetonitrile is also generated in situ by the reaction of acetonitrile with sulfur monochloride.
The aqueous solution consists of acrylonitrile, acetonitrile, hydrocyanic acid, and ammonium sulfate (from excess ammonia). A recovery column removes bulk water, and acrylonitrile and acetonitrile are separated by distillation. One of the first useful catalysts was bismuth phosphomolybdate (Bi 9 PMo 12 O 52) supported on silica. [11]
5'-Guanylyl imidodiphosphate (GDPNP) is a purine nucleotide.It is an analog of guanosine triphosphate in which one of the oxygen atoms is replaced with an amine, producing a non-hydrolyzable functional group.
Aminoacetonitrile is the organic compound with the formula H 2 N−CH 2 −C≡N.The compound is a colorless liquid. It is unstable at room temperature, owing to the incompatibility of the amine nucleophile and the nitrile electrophile.