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In case of optically active isotropic media, the rotation is the same for any direction of wave propagation. In contrast, the Faraday effect is non-reciprocal, i.e. opposite directions of wave propagation through a Faraday medium will result in clockwise and anti-clockwise polarization rotation from the point of view of an observer.
The CRC Handbook of Chemistry and Physics defines specific rotation as: For an optically active substance, defined by [α] θ λ = α/γl, where α is the angle through which plane polarized light is rotated by a solution of mass concentration γ and path length l.
In a symmetry group, the group elements are the symmetry operations (not the symmetry elements), and the binary combination consists of applying first one symmetry operation and then the other. An example is the sequence of a C 4 rotation about the z-axis and a reflection in the xy-plane, denoted σ(xy)C 4. By convention the order of operations ...
In the new coordinate system, the point P will appear to have been rotated in the opposite direction, that is, clockwise through the angle . A rotation of axes in more than two dimensions is defined similarly. [2] [3] A rotation of axes is a linear map [4] [5] and a rigid transformation.
In chemistry, it is the clockwise angle between half-planes through two sets of three atoms, having two atoms in common. In solid geometry, it is defined as the union of a line and two half-planes that have this line as a common edge. In higher dimensions, a dihedral angle represents the angle between two hyperplanes.
A sphere rotating (spinning) about an axis. Rotation or rotational motion is the circular movement of an object around a central line, known as an axis of rotation.A plane figure can rotate in either a clockwise or counterclockwise sense around a perpendicular axis intersecting anywhere inside or outside the figure at a center of rotation.
Clockwise motion (abbreviated CW) proceeds in the same direction as a clock's hands relative to the observer: from the top to the right, then down and then to the left, and back up to the top. The opposite sense of rotation or revolution is (in Commonwealth English ) anticlockwise ( ACW ) or (in North American English ) counterclockwise ( CCW ...
With the hydrogen atom away from the viewer, if the arrangement of the CO→R→N groups around the carbon atom as center is counter-clockwise, then it is the L form. [14] If the arrangement is clockwise, it is the D form. As usual, if the molecule itself is oriented differently, for example, with H towards the viewer, the pattern may be reversed.