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The molecular transfer equations of Newton's law for fluid momentum at low Reynolds number (Stokes flow), Fourier's law for heat, and Fick's law for mass are very similar, since they are all linear approximations to transport of conserved quantities in a flow field.
Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
There are some notable similarities in equations for momentum, energy, and mass transfer [7] which can all be transported by diffusion, as illustrated by the following examples: Mass: the spreading and dissipation of odors in air is an example of mass diffusion.
The convection–diffusion equation can be derived in a straightforward way [4] from the continuity equation, which states that the rate of change for a scalar quantity in a differential control volume is given by flow and diffusion into and out of that part of the system along with any generation or consumption inside the control volume: + =, where j is the total flux and R is a net ...
The Sherwood number (Sh) (also called the mass transfer Nusselt number) is a dimensionless number used in mass-transfer operation. It represents the ratio of the total mass transfer rate (convection + diffusion) to the rate of diffusive mass transport, [1] and is named in honor of Thomas Kilgore Sherwood. It is defined as follows
One more general framework is the Maxwell–Stefan diffusion equations [9] of multi-component mass transfer, from which Fick's law can be obtained as a limiting case, when the mixture is extremely dilute and every chemical species is interacting only with the bulk mixture and not with other species. To account for the presence of multiple ...
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
It is common in the field of mass transfer system design and modeling to draw analogies between heat transfer and mass transfer. [2] However, a mass transfer-analogous definition of the effectiveness-NTU method requires some additional terms. One common misconception is that gaseous mass transfer is driven by concentration gradients, however ...