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The creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. [2] Practical applications include the sparking mechanisms in lighters and various toys, using ferrocerium; starting fires without matches, using a firesteel; the flintlock mechanism in firearms; and spark testing ferrous metals.
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
tert-butyllithium is a pyrophoric substance, meaning that it spontaneously ignites on exposure to air. Air-free techniques are important so as to prevent this compound from reacting violently with oxygen and moisture: t-BuLi + O 2 → t-BuOOLi t-BuLi + H 2 O → t-BuH + LiOH. The solvents used in common commercial preparations are themselves ...
The gas produced by carbonization has a high content of carbon monoxide which is poisonous when breathed. Therefore, when working around the kiln or pit during operation and when the kiln is opened for unloading, care must be taken that proper ventilation is provided to allow the carbon monoxide, which is also produced during unloading through ...
As a pyrophoric substance, diborane reacts exothermically with oxygen to form boron trioxide and water: 2 B 2 H 6 + 6 O 2 → 2 B 2 O 3 + 6 H 2 O (ΔH r = −2035 kJ/mol = −73.47 kJ/g) Diborane reacts violently with water to form hydrogen and boric acid: B 2 H 6 + 6 H 2 O → 2 B(OH) 3 + 6 H 2 (ΔH r = −466 kJ/mol = −16.82 kJ/g) Diborane ...