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The reactions are shown below: Primary alcohols to carboxylic acids 4 CrO 3 + 3 RCH 2 OH + 12 H + → 3 RCOOH + 4 Cr 3+ + 9 H 2 O; Secondary alcohols to ketones 2 CrO 3 + 3 R 2 CHOH + 6 H + → 3 R 2 C=O + 2 Cr 3+ + 6 H 2 O
For oxidations to the aldehydes and ketones, two equivalents of chromic acid oxidize three equivalents of the alcohol: 2 HCrO 4 − + 3 RR'C(OH)H + 8 H + + 4 H 2 O → 2 [Cr(H 2 O) 6] 3+ + 3 RR'CO. For oxidation of primary alcohols to carboxylic acids, 4 equivalents of chromic acid oxidize 3 equivalents of the alcohol. The aldehyde is an ...
The complex is produced by treating chromium trioxide with pyridine. [2] The complex is diamagnetic. According to X-ray crystallography, the complex is 5-coordinate with mutually trans pyridine ligands.
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
Periodic Videos (also known as The Periodic Table of Videos) is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table , with additional videos on other topics in chemistry and related fields.
Potassium dichromate, K 2 Cr 2 O 7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health.
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The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...