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  2. Butyl group - Wikipedia

    en.wikipedia.org/wiki/Butyl_group

    The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.

  3. Butanol - Wikipedia

    en.wikipedia.org/wiki/Butanol

    Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).

  4. Steric effects - Wikipedia

    en.wikipedia.org/wiki/Steric_effects

    The parent cyclobutadiene (R = H) readily dimerizes but the R = tert-butyl derivative is robust. [1]Steric effects arise from the spatial arrangement of atoms. When atoms come close together there is generally a rise in the energy of the molecule.

  5. P4-t-Bu - Wikipedia

    en.wikipedia.org/wiki/P4-t-Bu

    P 4-t-Bu is a readily accessible chemical from the group of neutral, peralkylated sterically hindered polyaminophosphazenes, which are extremely strong bases but very weak nucleophiles, with the formula (CH 3) 3 C−N=P(−N=P(−N(CH 3) 2) 3) 3. "t-Bu" stands for tert-butyl (CH 3) 3 C –. "P 4" stands for the fact that this molecule has 4 ...

  6. tert-Butyl alcohol - Wikipedia

    en.wikipedia.org/wiki/Tert-Butyl_alcohol

    The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...

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  8. A value - Wikipedia

    en.wikipedia.org/wiki/A_value

    For example, the tert-butyl group (A-value=4.9) has a larger A-value than the trimethylsilyl group (A-value=2.5), yet the tert-butyl group actually occupies less space. This difference can be attributed to the longer length of the carbon–silicon bond as compared to the carbon–carbon bond of the tert-butyl group.

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