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Lee [4] developed a modified form of the Antoine equation that allows for calculating vapor pressure across the entire temperature range using the acentric factor (饾湐) of a substance. The fundamental structure of the equation is based on the van der Waals equation and builds upon the findings of Wall [ 5 ] and Gutmann et al. [ 6 ] , who ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
NIR absorption bands are typically 10–100 times weaker than the corresponding fundamental mid-IR absorption band.) [4] The lower absorption allows NIR radiation to penetrate much further into a sample than mid infrared radiation. Near-infrared spectroscopy is, therefore, not a particularly sensitive technique, but it can be very useful in ...
One way to write the van der Waals equation is: [8] [9] [10] = where is pressure, is temperature, and = / is molar volume. In addition is the Avogadro constant, is the volume, and is the number of molecules (the ratio / is a physical quantity with base unit mole (symbol mol) in the SI).
The first term in the equation represents this high-pressure behavior. The second term corrects for the attractive force of the molecules to each other. The functional form of a with respect to the critical temperature and pressure is empirically chosen to give the best fit at moderate pressures for most relatively non-polar gasses. [11]
Figure 1: Thermal pressure as a function of temperature normalized to A of the few compounds commonly used in the study of Geophysics. [3]The thermal pressure coefficient can be considered as a fundamental property; it is closely related to various properties such as internal pressure, sonic velocity, the entropy of melting, isothermal compressibility, isobaric expansibility, phase transition ...
The Sackur–Tetrode constant, written S 0 /R, is equal to S/k B N evaluated at a temperature of T = 1 kelvin, at standard pressure (100 kPa or 101.325 kPa, to be specified), for one mole of an ideal gas composed of particles of mass equal to the atomic mass constant (m u = 1.660 539 068 92 (52) × 10 −27 kg [5]).
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
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