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Toluene is widely used in the paint, dye, rubber, chemical, glue, printing, and pharmaceutical industries as a solvent. [38] Nail polish, paintbrush cleaners, and stain removers may contain toluene. Manufacturing of explosives (TNT) uses it as well. Toluene is also found in cigarette smoke and car exhaust.
Structures of the three isomers of tolyl group. In organic chemistry, tolyl groups are functional groups related to toluene. [1] They have the general formula CH 3 C 6 H 4 −R, the change of the relative position of the methyl and the R substituent on the aromatic ring can generate three possible structural isomers 1,2 (ortho), 1,3 (meta), and 1,4 (para).
Toluene (or methylbenzene) is a common chemical found in chemistry laboratories. An alkylbenzene is a chemical compound that contains a monocyclic aromatic ring attaching to one or more saturated hydrocarbon chains. [1] Alkylbenzenes are derivatives of benzene, in which one or more hydrogen atoms are replaced by alkyl groups.
Structure and properties Index of refraction, n D: 1.4969 at 20 °C Abbe number? Dielectric constant, ε r: 2.379 ε 0 at 25 °C Bond strength? Bond length? Bond angle? Magnetic susceptibility? Surface tension: 28.52 dyn/cm at 25 °C Viscosity [1]
TsOH is most often supplied as the monohydrate, and it may be necessary to remove the complexed water before use. Impurities can be removed by recrystallization from its concentrated aqueous solution followed by azeotropic drying with toluene. [2] TsOH finds use in organic synthesis as an "organic-soluble" strong acid. Examples of uses include:
In the petroleum refining and petrochemical industries, the initialism BTX refers to mixtures of benzene, toluene, and the three xylene isomers, all of which are aromatic hydrocarbons. The xylene isomers are distinguished by the designations ortho – (or o –), meta – (or m –), and para – (or p –) as indicated in the adjacent diagram.
The isotoluenes in organic chemistry are the non-aromatic toluene isomers with an exocyclic double bond. They are of some academic interest in relation to aromaticity and isomerisation mechanisms. [1] [2] The three basic isotoluenes are ortho-isotoluene or 5-methylene-1,3-cyclohexadiene (here labelled 1); para-isotoluene (2); and meta ...
Ethyltoluenes are prepared by alkylation of toluene with ethylene: CH 3 C 6 H 5 + CH 2 =CH 2 → CH 3 C 6 H 4 CH 2 CH 3. These alkylations are catalyzed by various Lewis acids, such as aluminium trichloride. 3- and 4-Ethyltoluenes are mainly of interest as precursors to methylstyrenes: CH 3 C 6 H 4 CH 2 CH 3 → CH 3 C 6 H 4 CH=CH 2 + H 2