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In his 1803 publication about the quantity of gases absorbed by water, [1] William Henry described the results of his experiments: … water takes up, of gas condensed by one, two, or more additional atmospheres, a quantity which, ordinarily compressed, would be equal to twice, thrice, &c. the volume absorbed under the common pressure of the atmosphere.
The amount of gas dissolved in a liquid is described by Henry's Law, which indicates that when the pressure of a gas in contact with a liquid is decreased, the amount of that gas dissolved in the liquid will also decrease proportionately. On ascent from a dive, inert gas comes out of solution in a process called "outgassing" or
Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. [2]
The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency.
In the ocean by volume, the most abundant gases dissolved in seawater are carbon dioxide (including bicarbonate and carbonate ions, 14 mL/L on average), nitrogen (9 mL/L), and oxygen (5 mL/L) at equilibrium at 24 °C (75 °F) [122] [123] [124] All gases are more soluble – more easily dissolved – in colder water than in warmer water. For ...
CaCO 3 is supersatured in the great majority of ocean surface waters and undersaturated at depth, [10] meaning the shells are more likely to dissolve as they sink to ocean depths. CaCO 3 can also be dissolved through metabolic dissolution (i.e. can be used as food and excreted) and thus deep ocean sediments have very little calcium carbonate. [16]
Inert gas such as nitrogen or helium continues to be taken up until the gas dissolved in the diver is in a state of equilibrium with the breathing gas in the diver's lungs, at which point the diver is saturated for that depth and breathing mixture, or the depth, and therefore the pressure, is changed, or the partial pressures of the gases are ...