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Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. [citation needed] The commonly known brand name of PTFE-based composition is Teflon by Chemours, [3] a spin-off from DuPont, which originally discovered the compound in 1938. [3]
Employing heat welding, tears can be repaired with a patch or multiple sheets assembled into larger panels. ETFE has an approximate tensile strength of 42 MPa (6100 psi), with a working temperature range of 89 K to 423 K ( −185 °C to +150 °C or −300 °F to +300 °F ).
Polytetrafluoroethylene (PTFE), better known by its trade name Teflon, has many desirable properties which make it an attractive material for numerous industries. It has good chemical resistance, a low dielectric constant, low dielectric loss, and a low coefficient of friction, making it ideal for reactor linings, circuit boards, and kitchen utensils, to name a few applications.
A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
Not all non-stick pans use Teflon; other non-stick coatings have become available. For example, a mixture of titanium and ceramic can be sandblasted onto the pan surface, and then fired at 2,000 °C (3,630 °F) to produce a non-stick ceramic coating. [19] Ceramic nonstick pans use a finish of silica (silicon dioxide) to prevent sticking.
MIL-T-27730A (an obsolete military specification still commonly used in industry in the US) requires a minimum thickness of 3.5 mils and a minimum PTFE purity of 99%. [3] The second standard, A-A-58092, [ 4 ] is a commercial grade which maintains the thickness requirement of MIL-T-27730A and adds a minimum density of 1.2 g/cm 3 . [ 4 ]
Extrusion of ECTFE fabric-backed sheets and subsequent fabrication into vessels, pipes or valves is done in the chemical industry. [14] [15] [16] Thick sheets are compression molded and can be manufactured to 50 mm in thickness. They are used in the semiconductor industry for wet benches or machining other parts.
Nafion derivatives are first synthesized by the copolymerization of tetrafluoroethylene (TFE) (the monomer in Teflon) and a derivative of a perfluoro (alkyl vinyl ether) with sulfonyl acid fluoride. The latter reagent can be prepared by the pyrolysis of its respective oxide or carboxylic acid to give the olefinated structure.
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