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An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :
The phase velocity is the rate at which the phase of the wave propagates in space. The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the profile of the wave amplitudes; all transverse displacements are bound by the envelope profile.
A so-called eigenmode is a solution that oscillates in time with a well-defined constant angular frequency ω, so that the temporal part of the wave function takes the form e −iωt = cos(ωt) − i sin(ωt), and the amplitude is a function f(x) of the spatial variable x, giving a separation of variables for the wave function: (,) = ().
A simple wave is a flow in a region adjacent to a region of constant state. [1] In the language of Riemann invariant , the simple wave can also be defined as the zone where all but one of the Riemann invariants are constant in the region of interest, and consequently, a simple wave zone is covered by arcs of characteristics that are straight lines.
In addition, an oscillating system may be subject to some external force, as when an AC circuit is connected to an outside power source. In this case the oscillation is said to be driven. The simplest example of this is a spring-mass system with a sinusoidal driving force.
The kinetic order of any elementary reaction or reaction step is equal to its molecularity, and the rate equation of an elementary reaction can therefore be determined by inspection, from the molecularity. [1] The kinetic order of a complex (multistep) reaction, however, is not necessarily equal to the number of molecules involved.
For example, a beam of electrons can be diffracted just like a beam of light or a water wave. The concept that matter behaves like a wave was proposed by French physicist Louis de Broglie ( / d ə ˈ b r ɔɪ / ) in 1924, and so matter waves are also known as de Broglie waves .
The standard example of a longitudinal wave is a sound wave or "pressure wave" in gases, liquids, or solids, whose oscillations cause compression and expansion of the material through which the wave is propagating. Pressure waves are called "primary waves", or "P-waves" in geophysics. Water waves involve both longitudinal and transverse motions ...