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Cadmia/tuttia/tutty – probably zinc carbonate. Calamine – zinc carbonate. Calomel/horn quicksilver/horn mercury – mercury(I) chloride, a very poisonous purgative formed by subliming a mixture of mercuric chloride and metallic mercury, triturated in a mortar and heated in an iron pot. The crust formed on the lid was ground to powder and ...
Zinc carbonate is the inorganic compound with the formula ZnCO 3. It is a white solid that is insoluble in water. It exists in nature as the mineral smithsonite. It is prepared by treating cold solutions of zinc sulfate with potassium bicarbonate. Upon warming, it converts to basic zinc carbonate (Zn 5 (CO 3) 2 (OH) 6). [6]
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.
Zinc powder is sometimes used as a propellant in model rockets. [154] When a compressed mixture of 70% zinc and 30% sulfur powder is ignited there is a violent chemical reaction. [154] This produces zinc sulfide, together with large amounts of hot gas, heat, and light. [154]
Solutions prepared from dissolving zinc hydroxide or zinc oxide in a strong alkali like sodium hydroxide, which contains various zincate anions, are used in the metal plating industry, in processes such as immersion zinc plating and electroplating (electrogalvanization). Any of these techniques may be called zincate process. [3]
Calamine is a historic name for an ore of zinc. The name calamine was derived from lapis calaminaris, a Latin correption of Greek cadmia (καδμία), the old name for zinc ores in general. The name of the Belgian town of Kelmis, La Calamine in French, which was home to a zinc mine, comes from this.
The zinc-chloride cell, frequently referred to as a heavy-duty, extra-heavy-duty, super-heavy-duty, or super-extra-heavy-duty battery, is an improvement on the original zinc–carbon cell, using purer chemicals and giving a longer service life and steadier voltage output as it is used and offering about twice the service life of general-purpose ...
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (Zn CO 3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion.
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