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Manual Control Chlorinator for the liquefaction of chlorine for water purification, early 20th century. From Chlorination of Water by Joseph Race, 1918. The first continuous use of chlorine in the United States for disinfection took place in 1908 at Boonton Reservoir (on the Rockaway River), which served as the supply for Jersey City, New ...
Chlorine is a respiratory irritant that attacks mucous membranes and burns the skin. As little as 3.53 ppm can be detected as an odor, and 1000 ppm is likely to be fatal after a few deep breaths. Exposure to chlorine has been limited to 0.5 ppm (8-hour time-weighted average—38-hour week) by the U.S. OSHA. [9]
Common examples include sodium hypochlorite (household bleach) and calcium hypochlorite (a component of bleaching powder, swimming pool "chlorine"). [1] The Cl-O distance in ClO − is 1.69 Å. [2] The name can also refer to esters of hypochlorous acid, namely organic compounds with a ClO– group covalently bound to the rest of the molecule.
Chlorine can be manufactured by the electrolysis of a sodium chloride solution , which is known as the Chloralkali process. The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2). These two products, as well as chlorine itself, are highly reactive.
Pure" samples have 99.2% active chlorine. Given common industrial purity, an active chlorine content of 65-70% is typical. [2] It is the main active ingredient of commercial products called bleaching powder, [a] used for water treatment and as a bleaching agent. [3]
Salt water chlorination is a process that uses dissolved salt (1000–4000 ppm or 1–4 g/L) for the chlorination of swimming pools and hot tubs.The chlorine generator (also known as salt cell, salt generator, salt chlorinator, or SWG) uses electrolysis in the presence of dissolved salt to produce chlorine gas or its dissolved forms, hypochlorous acid and sodium hypochlorite, which are already ...
This problem is avoided by the use of sodium hypochlorite, which is a relatively inexpensive solution used in household bleach that releases free chlorine when dissolved in water. Chlorine solutions can be generated on site by electrolyzing common salt solutions. A solid form, calcium hypochlorite, releases chlorine on contact with water ...
Chlorine, a powerful oxidizer, is the active agent in many household bleaches. Since pure chlorine is a toxic corrosive gas, these products usually contain hypochlorite, which releases chlorine. "Bleaching powder" usually refers to a formulation containing calcium hypochlorite. [citation needed]
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