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Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called the relative molar mass (M r). [8] This is a dimensionless quantity (i.e., a pure number, without units) equal to the molar mass divided by the molar mass constant .
When the molecular weight is given with the unit Da, it is frequently as a weighted average similar to the molar mass but with different units. In molecular biology, the mass of macromolecules is referred to as their molecular weight and is expressed in kDa, although the numerical value is often approximate and representative of an average.
The first absolute measurements of molecular weights (i.e. made without reference to standards) were based on fundamental physical characteristics and their relation to the molar mass. The most useful of these were membrane osmometry and sedimentation.
The Dumas method of molecular weight determination was historically a procedure used to determine the molecular weight of an unknown volatile substance. [ 1 ] [ 2 ] The method was designed by the French chemist Jean Baptiste André Dumas , after whom the procedure is now named.
The mass-average molecular mass, M w, is also related to the fractional monomer conversion, p, in step-growth polymerization (for the simplest case of linear polymers formed from two monomers in equimolar quantities) as per Carothers' equation: ¯ = + ¯ = (+), where M o is the molecular mass of the repeating unit.
Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight, abbreviated wt.% or % w/w; see mass versus weight). It is one way of expressing the composition of a mixture in a dimensionless size ; mole fraction (percentage by moles , mol%) and volume fraction ...
which can be used to relate the molecular weight of any two polymers using their Mark-Houwink constants (i.e. "universally" applicable for calibration). For example, if narrow molar mass distribution standards are available for polystyrene, these can be used to construct a calibration curve (typically l o g M {\displaystyle logM} vs. retention ...
The dalton (symbol: Da) is the standard unit that is used for indicating mass on an atomic or molecular scale (atomic mass). [1] The unified atomic mass unit (symbol: u) is equivalent to the dalton. One dalton is approximately the mass of one a single proton or neutron. [2] The unified atomic mass unit has a value of 1.660 538 921 (73) × 10 ...