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Displacement chromatography is a chromatography technique in which a sample is placed onto the head of the column [n 1] and is then displaced by a solute that is more strongly sorbed than the components of the original mixture.
A gas pycnometer is a laboratory device used for measuring the density—or, more accurately, the volume—of solids, be they regularly shaped, porous or non-porous, monolithic, powdered, granular or in some way comminuted, employing some method of gas displacement and the volume:pressure relationship known as Boyle's law.
In statistical mechanics, the mean squared displacement (MSD, also mean square displacement, average squared displacement, or mean square fluctuation) is a measure of the deviation of the position of a particle with respect to a reference position over time.
In fluid mechanics, displacement occurs when an object is largely immersed in a fluid, pushing it out of the way and taking its place. The volume of the fluid displaced can then be measured, and from this, the volume of the immersed object can be deduced: the volume of the immersed object will be exactly equal to the volume of the displaced fluid.
x is displacement; E(x) is energy; Q is the heat of adsorption or binding energy; a is the spacing between adjacent adsorption sites; E diff is the barrier to diffusion. Surface diffusion kinetics can be thought of in terms of adatoms residing at adsorption sites on a 2D lattice , moving between adjacent (nearest-neighbor) adsorption sites by a ...
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
They proved that the quaternion method is equivalent to the well-known Kabsch algorithm. [3] The solution given by Kabsch is an instance of the solution of the d-dimensional problem, introduced by Hurley and Cattell. [4] The quaternion solution to compute the optimal rotation was published in the appendix of a paper of Petitjean. [5]
An alternative to free-energy perturbation for computing potentials of mean force in chemical space is thermodynamic integration. Another alternative, which is probably more efficient, is the Bennett acceptance ratio method. Adaptations to FEP exist which attempt to apportion free-energy changes to subsections of the chemical structure. [5]