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Zn + H 2 SO 4 + 7 H 2 O → ZnSO 4 ·7H 2 O + H 2. Pharmaceutical-grade zinc sulfate is produced by treating high-purity zinc oxide with sulfuric acid: ZnO + H 2 SO 4 + 6 H 2 O → ZnSO 4 ·7H 2 O. In aqueous solution, all forms of zinc sulfate behave identically. These aqueous solutions consist of the metal aquo complex [Zn(H 2 O) 6] 2+ and SO ...
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 ...
In chemistry and thermodynamics, the standard enthalpy of formation or standard heat of formation of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements in their reference state, with all substances in their standard states. The standard pressure value p⦵ = 105 Pa (= 100 kPa = 1 ...
Standard electrode potential (data page) The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent ...
Single displacement reaction. A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [ 1 ][ 2 ][ 3 ] It can be represented generically as: where either.
Here are the two half-reactions: Oxidation: Zn → Zn 2+ + 2 e − Reduction: As 2 O 3 + 12 e − + 6 H + → 2 As 3− + 3 H 2 O. Overall, we have this reaction: As 2 O 3 + 6 Zn + 6 H + → 2 As 3− + 6 Zn 2+ + 3 H 2 O. In an acidic medium, As 3− is protonated to form arsine gas (AsH 3), so adding sulphuric acid (H 2 SO 4) to each side of ...
RXNO:0000369. The Friedel–Crafts reactions are a set of reactions developed by Charles Friedel and James Crafts in 1877 to attach substituents to an aromatic ring. [1] Friedel–Crafts reactions are of two main types: alkylation reactions and acylation reactions. Both proceed by electrophilic aromatic substitution. [2][3][4][5]
RXNO:0000226. The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. [1][2] In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.