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Lead (IV) hydroxide, Pb (OH)4, also called ortho-plumbic acid, is the notional conjugate acid of the ortho- plumbate (IV) ion, PbO4− 4, found in compounds such as calcium orthoplumbate, Ca2PbO4. [citation needed] Like its tin analog Sn (OH)4, Pb (OH)4 has not been isolated.
PbO 2 + 2 OH − + 2 H 2 O → Pb(OH) 2− 6. Lead also has an oxide with mixed +2 and +4 oxidation states, red lead (Pb 3 O 4), also known as minium. Lead readily forms an equimolar alloy with sodium metal that reacts with alkyl halides to form organometallic compounds of lead such as tetraethyllead. [4]
Careful hydrolysis of lead(II) acetate solution yields a crystalline product with a formula 6PbO·2H 2 O or Pb 6 O 4 (OH) 4. [3] This material is a cluster compound, consisting of an octahedron of Pb centers, each face of which is capped by an oxide or a hydroxide. The structure is reminiscent of the Mo 6 S 8 subunit of the Chevrel phases. [4]
PbSeO 4 Molar mass: 350.16 Appearance transparent solid [1] [2] Density: 6.37 g·cm −3 [2] Solubility in water. 130 mg/l at 25 °C [3] ... Pb 2+ + SeO 2− 4 → ...
Contents. Lead carbonate. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Lead (II) carbonate is the chemical compound with the chemical formula PbCO3. It is a white, toxic solid. [ 2 ] It occurs naturally as the mineral cerussite.
Lead's close-packed face-centered cubic structure and high atomic weight result in a density [23] of 11.34 g/cm 3, which is greater than that of common metals such as iron (7.87 g/cm 3), copper (8.93 g/cm 3), and zinc (7.14 g/cm 3). [24] This density is the origin of the idiom to go over like a lead balloon.
The basic hydroxo complex [Pb 6 O(OH) 6] 4+ is a cluster of six lead centres with metal–metal bonds surrounding a central oxide ion. The six hydroxide groups lie on the faces of the two external Pb 4 tetrahedra. In strongly alkaline solutions soluble plumbate ions are formed, including [Pb(OH) 6] 2−. [28]
2 Pb 12 O 17 → 8 Pb 3 O 4 + O 2 2 Pb 3 O 4 → 6 PbO + O 2. The stoichiometry of the end product can be controlled by changing the temperature – for example, in the above reaction, the first step occurs at 290 °C, second at 350 °C, third at 375 °C and fourth at 600 °C. In addition, Pb 2 O 3 can be obtained by decomposing PbO 2 at 580 ...