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Leaving group. In chemistry, a leaving group is defined by the IUPAC as an atom or group of atoms that detaches from the main or residual part of a substrate during a reaction or elementary step of a reaction. [ 1 ] However, in common usage, the term is often limited to a fragment that departs with a pair of electrons in heterolytic bond ...
The unimolecular nucleophilic substitution (SN1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses two properties—"S N " stands for "nucleophilic substitution", and the "1" says that the rate-determining step is unimolecular. [1][2] Thus, the rate equation is often shown as having ...
Carbonyl reduction. Oxidation ladders such as this one are used to illustrate sequences of carbonyls which can be interconverted through oxidations or reductions. In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced in many ways. [1]
The following is the reaction mechanism of a nucleophilic aromatic substitution of 2,4-dinitrochlorobenzene (1) in a basic solution in water. Nucleophilic aromatic substitution Since the nitro group is an activator toward nucleophilic substitution, and a meta director, it is able to stabilize the additional electron density (via resonance) when ...
An example of a solvolysis reaction is the reaction of a triglyceride with a simple alcohol such as methanol or ethanol to give the methyl or ethyl esters of the fatty acid, as well as glycerol. This reaction is more commonly known as a transesterification reaction due to the exchange of the alcohol fragments. [2]
Acyl group. A general acyl group (blue) in a ketone (top left), as an acylium cation (top centre), as an acyl radical (top right), an aldehyde (bottom left), ester (bottom centre) or amide (bottom right). (R1, R2 and R3 stands for organyl substituent or hydrogen in the case of R1) In chemistry, an acyl group is a moiety derived by the removal ...
The simplest primary alcohol is methanol (CH3OH), for which R = H, and the next is ethanol, for which R = CH3, the methyl group. Secondary alcohols are those of the form RR'CHOH, the simplest of which is 2-propanol (R = R' = CH3). For the tertiary alcohols, the general form is RR'R"COH.
Lucas' reagent. "Lucas' reagent" is a solution of anhydrous zinc chloride in concentrated hydrochloric acid. This solution is used to classify alcohols of low molecular weight. The reaction is a substitution in which the chloride replaces a hydroxyl group. A positive test is indicated by a change from clear and colourless to turbid, signalling ...