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The unimolecular nucleophilic substitution (SN1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses two properties—"S N " stands for "nucleophilic substitution", and the "1" says that the rate-determining step is unimolecular. [1][2] Thus, the rate equation is often shown as having ...
Leaving group. In chemistry, a leaving group is defined by the IUPAC as an atom or group of atoms that detaches from the main or residual part of a substrate during a reaction or elementary step of a reaction. [ 1 ] However, in common usage, the term is often limited to a fragment that departs with a pair of electrons in heterolytic bond ...
Solvolysis. In chemistry, solvolysis is a type of nucleophilic substitution (S N 1/S N 2) or elimination where the nucleophile is a solvent molecule. [ 1 ] Characteristic of S N 1 reactions, solvolysis of a chiral reactant affords the racemate. Sometimes however, the stereochemical course is complicated by intimate ion pairs, whereby the ...
Le Chatelier's principle applied to changes in concentration or pressure can be understood by giving K a constant value. The effect of temperature on equilibria, however, involves a change in the equilibrium constant. The dependence of K on temperature is determined by the sign of Δ H. The theoretical basis of this dependence is given by the ...
Carbonyl reduction. Oxidation ladders such as this one are used to illustrate sequences of carbonyls which can be interconverted through oxidations or reductions. In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced in many ways. [1]
HSAB theory. HSAB is an acronym for "hard and soft (Lewis) acids and bases ". HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species. 'Hard' applies to species which are small, have high charge states (the ...
Solvent effects. In chemistry, solvent effects are the influence of a solvent on chemical reactivity or molecular associations. Solvents can have an effect on solubility, stability and reaction rates and choosing the appropriate solvent allows for thermodynamic and kinetic control over a chemical reaction. A solute dissolves in a solvent when ...
In chemistry, an alcohol (from the Arabic word al-kuḥl, الكحل) is a type of organic compound that carries at least one hydroxyl (−OH) functional group bound to a saturated carbon atom. [ 2 ][ 3 ] Alcohols range from the simple, like methanol and ethanol, to complex, like sugars and cholesterol. The presence of an OH group strongly ...