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In chemistry, a half reaction (or half-cell reaction) is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Often, the concept of half reactions is used to describe what occurs in an ...
Redox (/ ˈrɛdɒks / RED-oks, / ˈriːdɒks / REE-doks, reduction–oxidation[2] or oxidation–reduction[3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4] Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the ...
Electrochemistry. English chemist John Daniell (left) and physicist Michael Faraday (right), both credited as founders of electrochemistry. Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an ...
In chemistry, disproportionation, sometimes called dismutation, is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation state. [1][2] The reverse of disproportionation, such as when a compound in an intermediate oxidation state is formed from precursors of ...
In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
A redox gradient is a series of reduction-oxidation (redox) reactions sorted according to redox potential. [ 4 ][ 5 ] The redox ladder displays the order in which redox reactions occur based on the free energy gained from redox pairs. [ 4 ][ 5 ][ 6 ] These redox gradients form both spatially and temporally as a result of differences in ...
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.
An electrolytic cell is an electrochemical cell in which applied electrical energy drives a non-spontaneous redox reaction. [5] A modern electrolytic cell consisting of two half reactions, two electrodes, a salt bridge, voltmeter, and a battery. They are often used to decompose chemical compounds, in a process called electrolysis.