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In the US, dimethyl carbonate was exempted under the definition of volatile organic compounds (VOCs) by the U.S. EPA in 2009. [9] Due to its classification as VOC exempt, dimethyl carbonate has grown in popularity and applications as a replacement for methyl ethyl ketone (MEK) and other solvents.
tert-Amyl methyl ether: 994-05-8 December 13, 2013 n-Butyl glycidyl ether: 2426-08-6 April 4, 2014 Chloramphenicol: 56-75-7 January 4, 2013 Chlorodibromomethane: 124-48-1 October 29, 1999 Chlorsulfuron: 64902-72-3 June 6, 2014 Cyclohexanol: 108-93-0 January 25, 2002 Diaminotoluene (mixed) – November 20, 2015 Dienestrol: 84-17-3 January 4 ...
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...
tert-Butyl acetate, t-butyl acetate or TBAc is a colorless flammable liquid with a camphor- or blueberry-like smell. It is used as a solvent in the production of lacquers, enamels, inks, adhesives, thinners and industrial cleaners. It has recently gained EPA volatile organic compound (VOC) exempt status. [3]
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Isobutanol (IUPAC nomenclature: 2-methylpropan-1-ol) is an organic compound with the formula (CH 3) 2 CHCH 2 OH (sometimes represented as i-BuOH).This colorless, flammable liquid with a characteristic smell is mainly used as a solvent either directly or as its esters.
tert-Butylthiol is the main ingredient in many gas odorant blends. [citation needed] It is always utilized as a blend of other compounds, typically dimethyl sulfide, methyl ethyl sulfide, tetrahydrothiophene or other mercaptans such as isopropyl mercaptan, sec-butyl mercaptan and/or n-butyl mercaptan, due to its rather high melting point of −0.5 °C (31.1 °F).
The MTBE controversy concerns methyl tert-butyl ether (MTBE), a gasoline additive that replaced tetraethyllead.MTBE is an oxygenate and raises gasoline's octane number.Its use declined in the United States in response to environmental and health concerns.