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In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound. The internal energy of a molecule consists of all the energy stored within it.
In organic chemistry, ring strain is a type of instability that exists when bonds in a molecule form angles that are abnormal. Strain is most commonly discussed for small rings such as cyclopropanes and cyclobutanes, whose internal angles are substantially smaller than the idealized value of approximately 109°.
Allylic strain in an olefin. Allylic strain (also known as A 1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin (a synonym for an alkene) with an allylic substituent on the other end. [1]
The activation strain model was originally proposed and has been extensively developed by Bickelhaupt and coworkers. [4] This model breaks the potential energy curve as a function of reaction coordinate, ζ, of a reaction into 2 components as shown in equation 1: the energy due to straining the original reactant molecules (∆E strain) and the energy due to interaction between reactant ...
Strain (biology), variants of biological organisms; Strain (chemistry), a chemical stress of a molecule; Strain (injury), an injury to a muscle; Strain (mechanics), a measure of deformation; Filtration, separating fluids from solids by passing through a filter; Percolation, of fluids through porous materials; Psychological stress
In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction. [1] The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy.
In organic chemistry, transannular strain (also called Prelog strain after chemist Vladimir Prelog) is the unfavorable interactions of ring substituents on non-adjacent carbons. These interactions, called transannular interactions, arise from a lack of space in the interior of the ring , which forces substituents into conflict with one another.
Click chemistry is an approach to chemical synthesis that emphasizes efficiency, simplicity, ... Scheme of the Strain-promoted Azide-Alkyne Cycloaddition.