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Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation ( α ) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ( [α] ) for the enantiopure compound is known.
Limonene (/ ˈ l ɪ m ə n ˌ iː n /) is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the essential oil of citrus fruit peels. [1] The (+)- isomer , occurring more commonly in nature as the fragrance of oranges, is a flavoring agent in food manufacturing.
the specific rotation of (S)-2-ethyl-2-methyl succinic acid is found to be dependent on concentration; in what is known as the Horeau effect [3] the relationship between mole based ee and optical rotation based ee can be non-linear i.d. in the succinic acid example the optical activity at 50% ee is lower than expected.
[citation needed] This dependence of specific rotation on wavelength is called optical rotatory dispersion. In all materials the rotation varies with wavelength. The variation is caused by two quite different phenomena. The first accounts in most cases for the majority of the variation in rotation and should not strictly be termed rotatory ...
Determination of specific rotation: In order to determine a specific rotation of an optically active substance (say, sugar), the polarimeter tube is first filled with pure water and the analyzer is adjusted for equal darkness (both the halves should be equally dark) point. The position of the analyzer is noted with the help of the scale.
Carvone may be synthetically prepared from limonene by first treating limonene nitrosyl chloride. Heating this nitroso compound gives carvoxime. Treating carvoxime with oxalic acid yields carvone. [14] This procedure affords R-(−)-carvone from R-(+)-limonene. The major use of d-limonene is as a precursor to S-(+)-carvone. The large scale ...
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials.
limonene-1,2-epoxide + H 2 O limonene-1,2-diol Thus, the two substrates of this enzyme are limonene-1,2-epoxide and H 2 O , whereas its product is limonene-1,2-diol. This enzyme is found in the bacterium Rhodococcus erythropolis DCL14, where it plays a role in the limonene degradation pathway that allows the bacteria to catabolize limonene as a ...