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Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner.
A good example of an incomplete separation technique is oil refining. Crude oil occurs naturally as a mixture of various hydrocarbons and impurities. The refining process splits this mixture into other, more valuable mixtures such as natural gas , gasoline and chemical feedstocks , none of which are pure substances, but each of which must be ...
In chemistry, bond cleavage, or bond fission, is the splitting of chemical bonds. This can be generally referred to as dissociation when a molecule is cleaved into two or more fragments. [1] In general, there are two classifications for bond cleavage: homolytic and heterolytic, depending on the nature of the process.
the work output W is the "noble" energy stored in the hydrogen and oxygen products (e.g. released as electricity during fuel consumption in a fuel cell). It thus corresponds to the free Gibbs energy change of water-splitting ΔG, and is maximum according to Eq.(3) at the lowest temperature of the process (T°) where it is equal to ΔG°.
Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the substance and water molecule to split into two parts. In such reactions, one fragment of the target molecule (or parent molecule) gains a hydrogen ion. It breaks a chemical bond in the compound.
In thermolysis, water molecules split into hydrogen and oxygen. For example, at 2,200 °C (2,470 K; 3,990 °F) about three percent of all H 2 O are dissociated into various combinations of hydrogen and oxygen atoms, mostly H, H 2, O, O 2, and OH. Other reaction products like H 2 O 2 or HO 2 remain minor. At the very high temperature of 3,000 ...
The split and pool synthesis (S&P synthesis) differs from traditional synthetic methods. The important novelty is the use of compound mixtures in the process. This is the reason of its unprecedentedly high productivity. Using the method one single chemist can make more compounds in a week than all chemists produced in the whole history of ...
The water-splitting reaction is catalyzed by the oxygen-evolving complex of photosystem II. This protein-bound inorganic complex contains four manganese ions, plus calcium and chloride ions as cofactors. Two water molecules are complexed by the manganese cluster, which then undergoes a series of four electron removals (oxidations) to replenish ...