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Internal conversion is an atomic decay process where an excited nucleus interacts electromagnetically with one of the orbital electrons of an atom. This causes the electron to be emitted (ejected) from the atom. [1] [2] Thus, in internal conversion (often abbreviated IC), a high-energy electron is emitted from the excited atom, but not from the ...
Internal conversion is a transition from a higher to a lower electronic state in a molecule or atom. [1] It is sometimes called "radiationless de-excitation", because no photons are emitted. It differs from intersystem crossing in that, while both are radiationless methods of de-excitation, the molecular spin state for internal conversion ...
The Hager-Seltzer calculations omit the M and higher-energy shells on the grounds (usually valid) that those orbitals have little electron density at the nucleus and can be neglected. To first approximation this assumption is valid, upon comparing several internal conversion coefficients for different isotopes for transitions of about 100 keV.
The electron–hole pair is the fundamental unit of generation and recombination in inorganic semiconductors, corresponding to an electron transitioning between the valence band and the conduction band where generation of an electron is a transition from the valence band to the conduction band and recombination leads to a reverse transition.
A second type of nonradiative transition is internal conversion (IC), which occurs when a vibrational state of an electronically excited state can couple to a vibrational state of a lower electronic state. The molecule could then subsequently relax further through vibrational relaxation.
A corollary of Kasha's rule is the Vavilov rule, which states that the quantum yield of luminescence is generally independent of the excitation wavelength. [4] [7] This can be understood as a consequence of the tendency – implied by Kasha's rule – for molecules in upper states to relax to the lowest excited state non-radiatively.
Feynman diagram of electron/positron annihilation. The electron–positron annihilation interaction: e + + e − → 2γ. has a contribution from the second order Feynman diagram: In the initial state (at the bottom; early time) there is one electron (e −) and one positron (e +) and in the final state (at the top; late time) there are two ...
In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.