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Since the pressure of the standard formation reaction is fixed at 1 bar, the standard formation enthalpy or reaction heat is a function of temperature. For tabulation purposes, standard formation enthalpies are all given at a single temperature: 298 K, represented by the symbol Δ f H ⦵ 298 K.
A temperature gradient is a physical quantity that describes in which direction and at what rate the temperature changes the most rapidly around a particular location. The temperature spatial gradient is a vector quantity with dimension of temperature difference per unit length. The SI unit is kelvin per meter (K/m).
The U.S. Standard Atmosphere model starts with many of the same assumptions as the isothermal-barotropic model, including ideal gas behavior, and constant molecular weight, but it differs by defining a more realistic temperature function, consisting of eight data points connected by straight lines; i.e. regions of constant temperature gradient.
Standard enthalpy of formation is the enthalpy change when one mole of any compound is formed from its constituent elements in their standard states. The enthalpy of formation of one mole of ethane gas refers to the reaction 2 C (graphite) + 3 H 2 (g) → C 2 H 6 (g).
Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Both of these definitions for the standard condition for pressure are in use.
The values used for M, g 0, and R * are in accordance with the U.S. Standard Atmosphere, 1976, and the value for R * in particular does not agree with standard values for this constant. [2] The reference value for P b for b = 0 is the defined sea level value, P 0 = 101 325 Pa or 29.92126 inHg.
The concept of potential temperature applies to any stratified fluid. It is most frequently used in the atmospheric sciences and oceanography. [2] The reason that it is used in both fields is that changes in pressure can result in warmer fluid residing under colder fluid – examples being dropping air temperature with altitude and increasing water temperature with depth in very deep ocean ...
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).