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Transition metal sulfito complexes are coordination compounds containing sulfite (SO 3 2-) as a ligand. The inventory is large. The inventory is large. Few sulfito complexes have commercial applications, but sulfite is a substrate for the molybdoenzyme sulfite oxidase .
Late transition metals are on the right side of the d-block, from group 8 to 11 (or 12, if they are counted as transition metals). In an alternative three-way scheme, groups 3, 4, and 5 are classified as early transition metals, 6, 7, and 8 are classified as middle transition metals, and 9, 10, and 11 (and sometimes group 12) are classified as ...
In monometallic complexes, aldehydes and ketones can bind to metals in either of two modes, η 1-O-bonded and η 2-C,O-bonded. These bonding modes are sometimes referred to sigma- and pi-bonded. These forms may sometimes interconvert. The sigma bonding mode is more common for higher valence, Lewis-acidic metal centers (e.g., Zn 2+). [1]
In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand. The class ...
Characteristically, transition metal alkoxides are polynuclear, that is they contain more than one metal. Alkoxides are sterically undemanding and highly basic ligands that tend to bridge metals. [citation needed] Upon the isomorphic substitution of metal atoms close in properties crystalline complexes of variable composition are formed.
Transition metal carbyne complexes are most common for the early transition metals, especially niobium, tantalum, molybdenum, tungsten, and rhenium. They can also have low-valence metals as well as high-valence metals. Protonation of a Re(I) vinylidene complex to give the corresponding cationic Re(V) carbyne derivative.
The bonding between alkenes and transition metals is described by the Dewar–Chatt–Duncanson model, which involves donation of electrons in the pi-orbital on the alkene to empty orbitals on the metal. This interaction is reinforced by back bonding that entails sharing of electrons in other metal orbitals into the empty pi-antibonding level ...
Transition metal alkyne complexes are often formed by the displacement of labile ligands by the alkyne. For example, a variety of cobalt-alkyne complexes arise by the reaction of alkynes with dicobalt octacarbonyl. [2] Co 2 (CO) 8 + R 2 C 2 → (R 2 C 2)Co 2 (CO) 6 + 2 CO. Many alkyne complexes are produced by reduction of metal halides: [3]