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This process is done by putting zinc or a zinc plated metal in a solution of sodium dichromate and sulfuric acid for a few seconds. [6] Zinc chromate can also be synthesized by using neutral potassium chromate (K 2 CrO 4) and zinc sulfate (ZnSO 4), which forms a precipitate. [7] K 2 CrO 4 + ZnSO 4 → ZnCrO 4 + K 2 SO 4
The chromate coating acts as paint does, protecting the zinc from white corrosion, thus making the part considerably more durable, depending on the chromate layer's thickness. [8] [9] [10] The protective effect of chromate coatings on zinc is indicated by color, progressing from clear/blue to yellow, gold, olive drab and black.
The Cronak process is a conventional chromate conversion coating process developed in 1933 by The New Jersey Zinc Company. [1] It involves immersing a zinc or zinc-plated article for 5 to 15 seconds in a chromate solution, typically prepared from sodium dichromate and sulfuric acid. [2]
Phosphate conversion coating is a chemical treatment applied to steel parts that creates a thin adhering layer of iron, zinc, or manganese phosphates to improve corrosion resistance or lubrication or as a foundation for subsequent coatings or painting. [1] [2] [3] It is one of the most common types of conversion coating.
The chromate and dichromate ions are fairly strong oxidizing agents. Commonly three electrons are added to a chromium atom, reducing it to oxidation state +3. In acid solution the aquated Cr 3+ ion is produced. Cr 2 O 2− 7 + 14 H + + 6 e − → 2 Cr 3+ + 7 H 2 O ε 0 = 1.33 V. In alkaline solution chromium(III) hydroxide is produced.
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This contained the chromic acid solution, the carbon plate and a porous pot. Inside the porous pot is dilute sulfuric acid, the zinc rod, and a small quantity of mercury. The mercury formed an amalgam with the zinc and this reduced "local action", i.e. unwanted dissolution of the zinc when the cell is not in use.
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