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The equations for relativistic quantum fields, of which the Klein–Gordon and Dirac equations are two examples, can be obtained in other ways, such as starting from a Lagrangian density and using the Euler–Lagrange equations for fields, or using the representation theory of the Lorentz group in which certain representations can be used to ...
The term "spin function" instead of "wave function" is used by some authors. This contrasts the solutions to position space wave functions, the position coordinates being continuous degrees of freedom, because then the Schrödinger equation does take the form of a wave equation.
The failure of classical mechanics applied to molecular, atomic, and nuclear systems and smaller induced the need for a new mechanics: quantum mechanics.The mathematical formulation was led by De Broglie, Bohr, Schrödinger, Pauli, and Heisenberg, and others, around the mid-1920s, and at that time was analogous to that of classical mechanics.
which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found.
A free particle with mass in non-relativistic quantum mechanics is described by the free Schrödinger equation: (,) = (,) where ψ is the wavefunction of the particle at position r and time t . The solution for a particle with momentum p or wave vector k , at angular frequency ω or energy E , is given by a complex plane wave :
The second term is the free particle propagator, corresponding to i times a diffusion process. To lowest order in ε they are additive; in any case one has with (1) : ψ ( y ; t + ε ) ≈ ∫ ψ ( x ; t ) e − i ε V ( x ) e i ( x − y ) 2 2 ε d x . {\displaystyle \psi (y;t+\varepsilon )\approx \int \psi (x;t)e^{-i\varepsilon V(x)}e^{\frac ...
The wave equation is a second-order linear partial differential equation for the description of waves or standing wave fields such as mechanical waves (e.g. water waves, sound waves and seismic waves) or electromagnetic waves (including light waves).
The Heisenberg picture is the closest to classical Hamiltonian mechanics (for example, the commutators appearing in the above equations directly translate into the classical Poisson brackets); but this is already rather "high-browed", and the Schrödinger picture is considered easiest to visualize and understand by most people, to judge from ...