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Chromium(III) oxide is amphoteric. Although insoluble in water, it reacts with acid to produce salts of hydrated chromium ions such as [Cr(H 2 O) 6] 3+. [11] It is also attacked by concentrated alkali to yield salts of [Cr(OH) 6] 3−. When heated with finely divided carbon or aluminium, it is reduced to chromium metal: Cr 2 O 3 + 2 Al → 2 Cr ...
Chromium(III) hydroxide (Cr(OH) 3) is amphoteric, dissolving in acidic solutions to form [Cr(H 2 O) 6] 3+, and in basic solutions to form [Cr(OH) 6] 3−. It is dehydrated by heating to form the green chromium(III) oxide (Cr 2 O 3), a stable oxide with a crystal structure identical to that of corundum. [6]
It is a black powder that crystallises in the rock salt structure. [2] Hypophosphites may reduce chromium(III) oxide to chromium(II) oxide: H 3 PO 2 + 2 Cr 2 O 3 → 4 CrO + H 3 PO 4. It is readily oxidized by the atmosphere. CrO is basic, while CrO 3 is acidic, and Cr 2 O 3 is amphoteric. [3]
Amphoteric is derived from the Greek word amphoteroi (ἀμφότεροι) meaning "both". Related words in acid-base chemistry are amphichromatic and amphichroic , both describing substances such as acid-base indicators which give one colour on reaction with an acid and another colour on reaction with a base.
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Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO 3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water ...
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al 2 O 3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and ...
The structure of the pyridine complex has been determined crystallographically. [2] Adducts with other N-heterocycles have also been characterized similarly. [3] Aqueous chromium(VI) oxide peroxide decomposes in a few seconds, turning green as chromium(III) compounds are formed. [4] 2 CrO(O 2) 2 + 7 H 2 O 2 + 6 H + → 2 Cr 3+ + 10 H 2 O + 7 O 2