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The second law of thermodynamics may be expressed in many specific ways, [23] the most prominent classical statements [24] being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms ...
The Planck statement applies only to perfect crystalline substances: As temperature falls to zero, the entropy of any pure crystalline substance tends to a universal constant. That is, lim T → 0 S = S 0 {\displaystyle \lim _{T\to 0}S=S_{0}} , where S 0 {\displaystyle S_{0}} is a universal constant that applies for all possible crystals, of ...
William Thomson, 1st Baron Kelvin (26 June 1824 – 17 December 1907 [7]), was a British mathematician, mathematical physicist and engineer. [8] [9] Born in Belfast, he was the professor of Natural Philosophy at the University of Glasgow for 53 years, where he undertook significant research and mathematical analysis of electricity, was instrumental in the formulation of the first and second ...
Boltzmann–Planck equation; Fokker–Planck equation; Nernst–Planck equation; Kelvin–Planck statement of the second law of thermodynamics; Massieu–Planck potentials; Planck potential; Planck proposition, Planck statement, Planck's principle; see Kelvin–Planck statement; Planckian locus
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
1 Clausius (Cl) = 1 calorie/degree Celsius (cal/°C) = 4.1868 joules per kelvin (J/K) The landmark 1865 paper in which he introduced the concept of entropy ends with the following summary of the first and second laws of thermodynamics: [4] The energy of the universe is constant. The entropy of the universe tends to a maximum.
The Clausius statement states that it is impossible to construct a device whose sole effect is the transfer of heat from a cool reservoir to a hot reservoir. [3] Equivalently, heat spontaneously flows from a hot body to a cooler one, not the other way around.
An example of a physical statement is that of Planck (1897/1903): It is in no way possible, either by mechanical, thermal, chemical, or other devices, to obtain perpetual motion, i.e. it is impossible to construct an engine which will work in a cycle and produce continuous work, or kinetic energy, from nothing. [33]