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Lithium imide is an inorganic compound with the chemical formula Li 2 N H. This white solid can be formed by a reaction between lithium amide and lithium hydride. [1] LiNH 2 + LiH → Li 2 NH + H 2. The product is light-sensitive and can undergo disproportionation to lithium amide and characteristically red lithium nitride. 2 Li 2 NH → LiNH 2 ...
Heating lithium amide with lithium hydride yields lithium imide and hydrogen gas. This reaction takes place as released ammonia reacts with lithium hydride. [2] Heating magnesium amide to about 400 °C yields magnesium imide with the loss of ammonia. Magnesium imide itself decomposes if heated between 455 and 490 °C. [6]
Lithium amide, when mixed with lithium hydride, shows applications in hydrogen storage. [4] [3] The reaction begins with lithium amide's decomposition into ammonia and lithium imide. Lithium hydride then deprotonates ammonia to form lithium amide. The reverse reaction can occur between hydrogen and the lithium imide side product.
The result is a condensation reaction: [5] (RCO) 2 O + R′NH 2 → (RCO) 2 NR′ + H 2 O. These reactions proceed via the intermediacy of amides. The intramolecular reaction of a carboxylic acid with an amide is far faster than the intermolecular reaction, which is rarely observed.
Under hydrogen at around 200°C, Li 3 N will react to form lithium amide. [10] Li 3 N + 2 H 2 → 2LiH + LiNH 2. At higher temperatures it will react further to form ammonia and lithium hydride. LiNH 2 + H 2 → LiH + NH 3. Lithium imide can also be formed under certain conditions. Some research has explored this as a possible industrial ...
Lithium–halogen exchange is a crucial part of Parham cyclization. [15] In this reaction, an aryl halide (usually iodide or bromide) exchanges with organolithium to form a lithiated arene species. If the arene bears a side chain with an electrophillic moiety, the carbanion attached to the lithium will perform intramolecular nucleophilic attack ...
Protic ionic liquids are formed via a proton transfer from an acid to a base. [26] In contrast to other ionic liquids, which generally are formed through a sequence of synthesis steps, [2] protic ionic liquids can be created more easily by simply mixing the acid and base. [26] Phosphonium cations (R 4 P +) are less common but offer some ...
Sample aldol reaction with lithium enolate. Lithium enolate formation can be generalized as an acid–base reaction, in which the relatively acidic proton α to the carbonyl group (pK =20-28 in DMSO) reacts with organolithium base. Generally, strong, non-nucleophilic bases, especially lithium amides such LDA, LiHMDS and LiTMP are used.