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Example of saponification reaction of a triglyceride molecule (left) with potassium hydroxide (KOH) yielding glycerol (purple) and salts of fatty acids ().. Saponification value or saponification number (SV or SN) represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified.
HLB scale showing classification of surfactant function. The hydrophilic–lipophilic balance (HLB) of a surfactant is a measure of its degree of hydrophilicity or lipophilicity, determined by calculating percentages of molecular weights for the hydrophilic and lipophilic portions of the surfactant molecule, as described by Griffin in 1949 [1] [2] and 1954. [3]
Upon introducing surfactants (or any surface active materials) into a system, they will initially partition into the interface, reducing the system free energy by: [citation needed] lowering the energy of the interface (calculated as area times surface tension), and; removing the hydrophobic parts of the surfactant from contact with water.
Some soap-makers leave the glycerol in the soap. Others precipitate the soap by salting it out with sodium chloride. Skeletal formula of stearin, a triglyceride that is converted by saponification with sodium hydroxide into glycerol and sodium stearate. Fat in a corpse converts into adipocere, often called "grave wax".
In this example, the surfactant molecules' oil-soluble tails project into the oil (blue), while the water-soluble ends remain in contact with the water phase (red). Surfactants are chemical compounds that decrease the surface tension or interfacial tension between two liquids, a liquid and a gas, or a liquid and a solid.
The principal historical use of these plants was boiling down to make soap. Saponaria officinalis is most suited for this procedure, but other related species also work. The greatest concentration of saponin occurs during flowering, with the most saponin found in the woody stems and roots, but the leaves also contain some.
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The Krafft temperature is a point of phase change below which the surfactant remains in crystalline form, even in an aqueous solution. Visually the effect of going below the Krafft point is similar to that of going above the cloud point, with the solution becoming cloudy or opaque due to the surfactant molecules undergoing flocculation.