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In chemistry and physics, the exchange interaction is a quantum mechanical constraint on the states of indistinguishable particles.While sometimes called an exchange force, or, in the case of fermions, Pauli repulsion, its consequences cannot always be predicted based on classical ideas of force. [1]
The effect is a result of an electric field produced by charge localization in a molecule. [1] This field, which is substituent and conformation dependent, can influence structure and reactivity by manipulating the location of electron density in bonds and/or the overall molecule. [ 2 ]
In chemistry and physics, cohesion (from Latin cohaesiō 'cohesion, unity'), also called cohesive attraction or cohesive force, is the action or property of like molecules sticking together, being mutually attractive.
Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science.
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. [1]: xi QFT is used in particle physics to construct physical models of subatomic particles and in condensed matter physics to construct models of quasiparticles.
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles.By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon.
The Planck constant, or Planck's constant, denoted by , [1] is a fundamental physical constant [1] of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a matter wave equals the Planck constant divided by the associated particle momentum.
Field effect may refer to: relative influence of electricity to the substrate within a given field. Field effect (chemistry), an effect that a pole (either an unipole or dipole) has on a remote reaction centre (reaction rates, equilibrium). This effect operates through space not through bonds which distinguishes it from the inductive effect.