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Hexagonal close packed (hcp) unit cell. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face-centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice, as there are two nonequivalent sets of lattice points.
Many crystal structures are based on a close-packing of a single kind of atom, or a close-packing of large ions with smaller ions filling the spaces between them. The cubic and hexagonal arrangements are very close to one another in energy, and it may be difficult to predict which form will be preferred from first principles.
For the hexagonal close-packed structure the derivation is similar. Here the unit cell (equivalent to 3 primitive unit cells) is a hexagonal prism containing six atoms (if the particles in the crystal are atoms).
This arrangement of atoms in a crystal structure is known as hexagonal close packing (hcp). If, however, all three planes are staggered relative to each other and it is not until the fourth layer is positioned directly over plane A that the sequence is repeated, then the following sequence arises:
In closest packing, every atom has 12 equidistant nearest neighbours, and therefore a coordination number of 12. If the close packed structures are considered as being built of layers of spheres, then the difference between hexagonal close packing and face-centred cubic is how each layer is positioned relative to others.
A close packed unit cell, both face-centered cubic and hexagonal close packed, can form two different shaped holes. Looking at the three green spheres in the hexagonal packing illustration at the top of the page, they form a triangle-shaped hole. If an atom is arranged on top of this triangular hole it forms a tetrahedral interstitial hole.
2.3.6 Hexagonal close-packed (HCP) ... The crystal structure can be described as a Bravais lattice with a group of atoms, called the basis, ...
This category lists every chemical element that exists in a hexagonal close packed structure at STP. Pages in category "Chemical elements with hexagonal close-packed structure" The following 27 pages are in this category, out of 27 total.