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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
tert-Butyl alcohol is the simplest tertiary alcohol, with a formula of (CH 3) 3 COH (sometimes represented as t -BuOH). Its isomers are 1-butanol, isobutanol, and butan-2-ol. tert -Butyl alcohol is a colorless solid, which melts near room temperature and has a camphor -like odor. It is miscible with water, ethanol and diethyl ether.
Infobox references. tert-Butyl acetate, t -butyl acetate or TBAc is a colorless flammable liquid with a camphor - or blueberry -like smell. It is used as a solvent in the production of lacquers, enamels, inks, adhesives, thinners and industrial cleaners. It has recently gained EPA volatile organic compound (VOC) exempt status.
n-Butyl acetate is an organic compound with the formula CH 3 CO 2 (CH 2) 3 CH 3. A colorless, flammable liquid, it is the ester derived from n- butanol and acetic acid . It is found in many types of fruit, where it imparts characteristic flavors and has a sweet smell of banana or apple.
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
tert-Butyl hydroperoxide (tBuOOH) is the organic compound with the formula (CH 3) 3 COOH. It is one of the most widely used hydroperoxides in a variety of oxidation processes, like the Halcon process. [3] It is normally supplied as a 69–70% aqueous solution. Compared to hydrogen peroxide and organic peracids, tert -butyl hydroperoxide is less ...
Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH 3) 3 COCH 3. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. [1] Primarily used as a fuel additive, MTBE is blended into gasoline to increase its octane rating and knock resistance ...
tert-Butyl chloride is the organochloride with the formula (CH3)3CCl. It is a colorless, flammable liquid. It is sparingly soluble in water, with a tendency to undergo hydrolysis to the corresponding tert -butyl alcohol. It is produced industrially as a precursor to other organic compounds. [1]
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