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Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Iron oxides feature as ferrous or ferric or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are significant at the earth's surface, particularly wüstite, magnetite, and hematite. Oxides of Fe II. FeO: iron(II) oxide, wüstite; Mixed oxides of Fe II and Fe III. Fe 3 O 4: Iron(II,III) oxide, magnetite; Fe 4 O ...
Iron(II,III) oxide, or black iron oxide, is the chemical compound with formula Fe 3 O 4. It occurs in nature as the mineral magnetite . It is one of a number of iron oxides , the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe 2 O 3 ) which also occurs naturally as the mineral hematite .
The term kidney ore may be broadly used to describe botryoidal, mammillary, or reniform hematite. [8] Maghemite is a polymorph of hematite (γ-Fe 2 O 3) with the same chemical formula, but with a spinel structure like magnetite. Large deposits of hematite are found in banded iron formations.
Of the iron ore exported, 38.5% of the volume was iron ore pellets with a value of $2.3 billion, and 61.5% was iron ore concentrates with a value of $2.3 billion. [40] 46% of Canada's iron ore comes from the Iron Ore Company of Canada mine, in Labrador City, Newfoundland, with secondary sources including the Mary River Mine in Nunavut. [40] [41]
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
The structure is inverse spinel, with O 2-ions forming a face-centered cubic lattice and iron cations occupying interstitial sites. Half of the Fe 3+ cations occupy tetrahedral sites while the other half, along with Fe 2+ cations, occupy octahedral sites. The unit cell consists of thirty-two O 2-ions and unit cell length is a = 0.839 nm. [15] [16]
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.