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Probability. Step-growth polymerization is a random process so we can use statistics to calculate the probability of finding a chain with x-structural units ("x-mer") as a function of time or conversion. Probability that an 'A' functional group has reacted. Probability of finding an 'A' unreacted.
The simplest case refers to the formation of a strictly linear polymer by the reaction (usually by condensation) of two monomers in equimolar quantities. An example is the synthesis of nylon-6,6 whose formula is [−NH−(CH 2) 6 −NH−CO−(CH 2) 4 −CO−] n from one mole of hexamethylenediamine, H 2 N(CH 2) 6 NH 2, and one mole of adipic acid, HOOC−(CH 2) 4 −COOH.
When a partial fraction term has a single (i.e. unrepeated) binomial in the denominator, the numerator is a residue of the function defined by the input fraction. We calculate each respective numerator by (1) taking the root of the denominator (i.e. the value of x that makes the denominator zero) and (2) then substituting this root into the ...
Composite Simpson's 3/8 rule is even less accurate. Integration by Simpson's 1/3 rule can be represented as a weighted average with 2/3 of the value coming from integration by the trapezoidal rule with step h and 1/3 of the value coming from integration by the rectangle rule with step 2h. The accuracy is governed by the second (2h step) term
Semitone. A semitone, also called a minor second, half step, or a half tone, [3] is the smallest musical interval commonly used in Western tonal music, [4] and it is considered the most dissonant [5] when sounded harmonically. It is defined as the interval between two adjacent notes in a 12-tone scale (or half of a whole step), visually seen on ...
Indeed, three are the atoms in the middle layer (inside the prism); in addition, for the top and bottom layers (on the bases of the prism), the central atom is shared with the adjacent cell, and each of the six atoms at the vertices is shared with other six adjacent cells. So the total number of atoms in the cell is 3 + (1/2)×2 + (1/6)×6×2 = 6.
A sieve analysis (or gradation test) is a practice or procedure used in geology, civil engineering, [1] and chemical engineering [2] to assess the particle size distribution (also called gradation) of a granular material by allowing the material to pass through a series of sieves of progressively smaller mesh size and weighing the amount of material that is stopped by each sieve as a fraction ...
Step function. In mathematics, a function on the real numbers is called a step function if it can be written as a finite linear combination of indicator functions of intervals. Informally speaking, a step function is a piecewise constant function having only finitely many pieces. An example of step functions (the red graph).