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Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.
A network covalent solid consists of atoms held together by a network of covalent bonds (pairs of electrons shared between atoms of similar electronegativity), and hence can be regarded as a single, large molecule. The classic example is diamond; other examples include silicon, [3] quartz and graphite.
[3] If a bond strength is higher than 80 kcal per bond (high bond strength), it will be glass network forming, meaning it is likely to form a glass. If a bond strength is less than 60 kcal per bond (low bond strength), it will be glass network modifying, since it would only form weak bonds, it would disrupt glass forming networks.
An early instance of polyhedral nets appears in the works of Albrecht Dürer, whose 1525 book A Course in the Art of Measurement with Compass and Ruler (Unterweysung der Messung mit dem Zyrkel und Rychtscheyd ) included nets for the Platonic solids and several of the Archimedean solids. [2] [3] These constructions were first called nets in 1543 ...
The rhombic dodecahedron is a Catalan solid, meaning the dual polyhedron of an Archimedean solid, the cuboctahedron; they share the same symmetry, the octahedral symmetry. [2] It is face-transitive , meaning the symmetry group of the solid acts transitively on its set of faces.
These tetrahedrons together form a 3-dimensional network of six-membered carbon rings in the chair conformation, allowing for zero bond angle strain. The bonding occurs through sp 3 hybridized orbitals to give a C-C bond length of 154 pm. This network of unstrained covalent bonds makes diamond extremely strong.
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The number of coordination bonds (coordination number) can vary from two in K[Ag(CN) 2] as high as 20 in Th(η 5-C 5 H 5) 4. [ 2 ] One of the most common coordination geometries is octahedral , where six ligands are coordinated to the metal in a symmetrical distribution, leading to the formation of an octahedron if lines were drawn between the ...