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Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO 2, commonly found in nature as quartz. [5] [6] In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product.
A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms , with oxygen taking the larger share due to its greater electronegativity .
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide).The atoms are linked in a continuous framework of SiO 4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO 2.
Formulas for network solids, like those for ionic compounds, are simple ratios of the component atoms represented by a formula unit. [3] Examples of network solids include diamond with a continuous network of carbon atoms and silicon dioxide or quartz with a continuous three-dimensional network of SiO 2 units.
The general formula is (Si x O 3x) 2x−, where one or more silicon atoms can be replaced by other 4-coordinated atom(s). The silicon:oxygen ratio is 1:3. Double rings have the formula (Si 2x O 5x) 2x− or a 2:5 ratio. The Nickel–Strunz classification is 09.C. Possible ring sizes include:
2 has an overall charge of −1, so each of its two equivalent oxygen atoms is assigned an oxidation state of − 1 / 2 . This ion can be described as a resonance hybrid of two Lewis structures, where each oxygen has an oxidation state of 0 in one structure and −1 in the other.
The shift from the hypoelectronic elements in Group 13 and earlier to the Group 14 elements is illustrated by the change from an infinite ionic structure in aluminium fluoride to a lattice of simple covalent silicon tetrafluoride molecules, as dictated by the lower electronegativity of aluminium than silicon, the stoichiometry (the +4 oxidation ...
Silicon forms several hydrides; two of them are SiH 4 and Si 2 H 6. Silicon forms tetrahalides with fluorine (SiF 4), chlorine (SiCl 4), bromine (SiBr 4), and iodine (SiI 4). Silicon also forms a dioxide and a disulfide. [5] Silicon nitride has the formula Si 3 N 4. [6] Germanium forms five hydrides. The first two germanium hydrides are GeH 4 ...