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The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction.
A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
The equivalence point occurs between pH 8-10, indicating the solution is basic at the equivalence point and an indicator such as phenolphthalein would be appropriate. Titration curves corresponding to weak bases and strong acids are similarly behaved, with the solution being acidic at the equivalence point and indicators such as methyl orange ...
where " φ = fraction of completion of the titration (φ < 1 is before the equivalence point, φ = 1 is the equivalence point, and φ > 1 is after the equivalence point) Monoprotic acid titration curve. Highlighted pink region depicts equivalence point., = the concentrations of the acid and base respectively
A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the equivalence volume or end point in a strong acid-strong base titration or in a potentiometric titration.
The end point is detected most commonly by a bipotentiometric titration method. A second pair of Pt electrodes is immersed in the anode solution. The detector circuit maintains a constant current between the two detector electrodes during titration. Prior to the equivalence point, the solution contains I − but little I 2.
Animation of a strong acid–strong base neutralization titration (using phenolphthalein).The equivalence point is marked in red. In chemistry, neutralization or neutralisation (see spelling differences) is a chemical reaction in which acid and a base react with an equivalent quantity of each other.
V eq is the volume of titrant (ml) consumed by the crude oil sample and 1 ml of spiking solution at the equivalent point, b eq is the volume of titrant (ml) consumed by 1 ml of spiking solution at the equivalent point, 56.1 g/mol is the molecular weight of KOH, W oil is the mass of the sample in grams. The normality (N) of titrant is calculated as: