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Row 21. Values of the seven parameters for the fifth ΔG° form equation; temperature limit for the equation. Most computerized databases will create a table of thermodynamic values using the values from the datafile. For MgCl 2 (c,l,g) at 1 atm pressure: Thermodynamic properties table for MgCl 2 (c,l,g), from the FREED datafile. Some values ...
Acetonitrile is less basic than DMSO, and, so, in general, acids are weaker and bases are stronger in this solvent. Some pK a values at 25 °C for acetonitrile (ACN) [37] [38] [39] and dimethyl sulfoxide (DMSO). [40] are shown in the following tables. Values for water are included for comparison.
2 and 20 percent oxygen O 2. Both molecules are small and non-polar (and therefore non-associating). We can therefore expect that the behaviour of air within broad temperature and pressure ranges can be approximated as an ideal gas with reasonable accuracy. Experimental values for the compressibility factor confirm this.
The higher the proton affinity, the stronger the base and the weaker the conjugate acid in the gas phase.The (reportedly) strongest known base is the ortho-diethynylbenzene dianion (E pa = 1843 kJ/mol), [3] followed by the methanide anion (E pa = 1743 kJ/mol) and the hydride ion (E pa = 1675 kJ/mol), [4] making methane the weakest proton acid [5] in the gas phase, followed by dihydrogen.
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
Solid oxygen forms at normal atmospheric pressure at a temperature below 54.36 K (−218.79 °C, −361.82 °F). Solid oxygen O 2 , like liquid oxygen , is a clear substance with a light sky-blue color caused by absorption in the red part of the visible light spectrum.
Its bulk properties partly result from the interaction of its component atoms, oxygen and hydrogen, with atoms of nearby water molecules. Hydrogen atoms are covalently bonded to oxygen in a water molecule but also have an additional attraction (about 23.3 kJ·mol −1 per hydrogen atom) to an adjacent oxygen atom in a separate molecule. [ 2 ]
In its path, a PKA can produce effects similar to those of heating and rapidly quenching a metal, resulting in Frenkel defects. A thermal spike does not last long enough to permit annealing of the Frenkel defects. [1] [2] A different model called the displacement spike was proposed for fast neutron bombardment of heavy elements.