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Bloch's theorem — For electrons in a perfect crystal, there is a basis of wave functions with the following two properties: each of these wave functions is an energy eigenstate,
The boundaries of this cell are given by planes related to points on the reciprocal lattice. The importance of the Brillouin zone stems from the description of waves in a periodic medium given by Bloch's theorem, in which it is found that the solutions can be completely characterized by their behavior in a single Brillouin zone.
Bloch's theorem was inspired by the following theorem of Georges Valiron: Theorem. If f is a non-constant entire function then there exist disks D of arbitrarily large radius and analytic functions φ in D such that f(φ(z)) = z for z in D. Bloch's theorem corresponds to Valiron's theorem via the so-called Bloch's principle.
The Bloch's function is an exact eigensolution for the wave function of an electron in a periodic crystal potential corresponding to an energy (), and is spread over the entire crystal volume. Using the Fourier transform analysis, a spatially localized wave function for the m -th energy band can be constructed from multiple Bloch's functions:
Using Bloch's theorem, we only need to find a solution for a single period, make sure it is continuous and smooth, and to make sure the function u(x) is also continuous and smooth. Considering a single period of the potential: We have two regions here. We will solve for each independently: Let E be an energy value above the well (E>0)
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
The theorem arises as a direct consequence of the aforementioned fact that the lattice symmetry translation operator commutes with the system's Hamiltonian. [ 3 ] : 261–266 [ 5 ] One of the notable aspects of Bloch's theorem is that it shows directly that steady state solutions may be identified with a wave vector k {\displaystyle \mathbf {k ...
This is a list of notable theorems. Lists of theorems and similar statements include: List of algebras; List of algorithms; List of axioms; List of conjectures; List of data structures; List of derivatives and integrals in alternative calculi; List of equations; List of fundamental theorems; List of hypotheses; List of inequalities; Lists of ...