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In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition.
There is a fact, or if you wish, a law, governing all natural phenomena that are known to date. There is no known exception to this law – it is exact so far as we know. The law is called the conservation of energy. It states that there is a certain quantity, which we call energy, that does not change in manifold changes which nature undergoes.
This is an accepted version of this page This is the latest accepted revision, reviewed on 24 February 2025. Law of physics and chemistry This article is about the law of conservation of energy in physics. For sustainable energy resources, see Energy conservation. Part of a series on Continuum mechanics J = − D d φ d x {\displaystyle J=-D{\frac {d\varphi }{dx}}} Fick's laws of diffusion ...
When a voltmeter is used to measure an electronic device, it does not quite measure the pure electric potential (also called Galvani potential).Instead, it measures the electrochemical potential, also called "fermi level difference", which is the total free energy difference per electron, including not only its electric potential energy but also all other forces and influences on the electron ...
Mathematically, we can state the law of charge conservation as a continuity equation: = ˙ ˙ (). where / is the electric charge accumulation rate in a specific volume at time t, ˙ is the amount of charge flowing into the volume and ˙ is the amount of charge flowing out of the volume; both amounts are regarded as generic functions of time.
All of the conservation laws listed above are local conservation laws. A local conservation law is expressed mathematically by a continuity equation, which states that the change in the quantity in a volume is equal to the total net "flux" of the quantity through the surface of the volume. The following sections discuss continuity equations in ...
Quantum electron energy states for electron are found using the electron quantum Hamiltonian, which is generally composed of kinetic (-ħ 2 ∇ 2 /2m e) and potential energy terms (φ e). Atomic orbital, a mathematical function describing the wave-like behavior of either an electron or a pair of electrons in an atom , can be found from the ...