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Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
A diatomic gas is axially symmetric about only one axis, so that D = 5, comprising translational motion along three axes and rotational motion along two axes. A polyatomic gas, like water, is not radially symmetric about any axis, resulting in D = 6, comprising 3 translational and 3 rotational degrees of freedom.
In physics, engineering, and physical chemistry, a perfect gas is a theoretical gas model that differs from real gases in specific ways that makes certain calculations easier to handle. In all perfect gas models, intermolecular forces are neglected. This means that one can neglect many complications that may arise from the Van der Waals forces.
Once the constants and are experimentally determined for a given substance, the van der Waals equation can be used to predict attributes like the boiling point at any given pressure, and the critical point (defined by pressure and temperature such that the substance cannot be liquefied either when > no matter how low the temperature, or when ...
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
The standard unit is the meter cubed per kilogram (m 3 /kg or m 3 ·kg −1). Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance. In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely ...
If the gas is heated so that the temperature of the gas goes up to T 2 while the piston is allowed to rise to V 2 as in Figure 1, then the pressure is kept the same in this process due to the free floating piston being allowed to rise making the process an isobaric process or constant pressure process. This Process Path is a straight horizontal ...
where P is the pressure of the gas, V is the volume of the gas, and k is a constant for a particular temperature and amount of gas. Boyle's law states that when the temperature of a given mass of confined gas is constant, the product of its pressure and volume is also constant. When comparing the same substance under two different sets of ...