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  2. Robert Bruce Merrifield - Wikipedia

    en.wikipedia.org/wiki/Robert_Bruce_Merrifield

    These studies led to the need for peptide synthesis and, eventually, to the idea for solid phase peptide synthesis (SPPS) in 1959. In 1963, he was sole author of a classic paper in the Journal of the American Chemical Society in which he reported a method he called "solid phase peptide synthesis". [4]

  3. Solid-phase synthesis - Wikipedia

    en.wikipedia.org/wiki/Solid-phase_synthesis

    The solid phase now bears a dipeptide. This cycle is repeated to form the desired peptide chain. After all reactions are complete, the synthesised peptide is cleaved from the bead. The protecting groups for the amino groups mostly used in the peptide synthesis are 9-fluorenylmethyloxycarbonyl group and t-butyloxycarbonyl . A number of amino ...

  4. Peptide synthesis - Wikipedia

    en.wikipedia.org/wiki/Peptide_synthesis

    The established method for the production of synthetic peptides in the lab is known as solid phase peptide synthesis (SPPS). [2] Pioneered by Robert Bruce Merrifield, [4] [5] SPPS allows the rapid assembly of a peptide chain through successive reactions of amino acid derivatives on a macroscopically insoluble solvent-swollen beaded resin support.

  5. Combinatorial chemistry - Wikipedia

    en.wikipedia.org/wiki/Combinatorial_chemistry

    Combinatorial split-mix (split and pool) synthesis [12] [13] is based on the solid-phase synthesis developed by Merrifield. [14] If a combinatorial peptide library is synthesized using 20 amino acids (or other kinds of building blocks) the bead form solid support is divided into 20 equal portions. This is followed by coupling a different amino ...

  6. Pseudoproline - Wikipedia

    en.wikipedia.org/wiki/Pseudoproline

    Due to the preference for a cis-amide bond [10] with the preceding residue of C2-substituted pseudoprolines, their incorporation results in a kink conformation of the peptide backbone, thus preventing peptide aggregation, self-association, or β-structure formation. Strategies for the use of Pseudoproline in Solid-Phase Peptide Synthesis (SPPS).

  7. Fluorenylmethyloxycarbonyl protecting group - Wikipedia

    en.wikipedia.org/wiki/Fluorenylmethyloxycarbonyl...

    The fluorenylmethoxycarbonyl protecting group (Fmoc) is a base-labile amine protecting group used in organic synthesis, particularly in peptide synthesis [1]. It is popular for its stability toward acids and hydrolysis and its selective removal by weak bases, such as piperidine , without affecting most other protecting groups or sensitive ...

  8. Peptide library - Wikipedia

    en.wikipedia.org/wiki/Peptide_library

    A peptide library is a tool for studying proteins. Peptide libraries typically contain a large number of peptides that have a systematic combination of amino acids. Usually, solid phase synthesis, e.g. resin as a flat surface or beads, is used for peptide library generation.

  9. Custom peptide synthesis - Wikipedia

    en.wikipedia.org/wiki/Custom_peptide_synthesis

    Solid phase peptide synthesis Custom peptide synthesis is the commercial production of peptides for use in biochemistry , biology, biotechnology, pharmacology and molecular medicine . [ 1 ] Custom peptide synthesis provides synthetic peptides as valuable tools to biomedical laboratories.

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